Characterization of PVA-Enzyme Coated Indicator Electrodes GA coated again with PVC-KTpClPB-o-NPOE SEM-EDS, FTIR and XRD analysis

Authors

Abd Hakim S

DOI:

10.29303/jppipa.v8i1.1265

Published:

2022-01-08

Issue:

Vol. 8 No. 1 (2022): January

Keywords:

Tungsten indicator electrodes, GA and o-NPOE, SEM-EDS, FTIR and XRD, Biosensor Potentiometry, Immobilization

Research Articles

Downloads

How to Cite

S, A. H. (2022). Characterization of PVA-Enzyme Coated Indicator Electrodes GA coated again with PVC-KTpClPB-o-NPOE SEM-EDS, FTIR and XRD analysis. Jurnal Penelitian Pendidikan IPA, 8(1), 103–108. https://doi.org/10.29303/jppipa.v8i1.1265

Downloads

Download data is not yet available.

Metrics

Metrics Loading ...

Abstract

This study aims to characterize the tungsten-urea analyte indicator electrode. The method used is biosensor potentiometry with urease enzyme immobilization technique. This indicator electrode was coated with PVA-enzyme coated with glutaraldehyde (GA) 2.9% coated with PVC-KTpClPB- o-NPOE with o-NPOE variation of 61% and 66%. Characterization of coated indicator electrodes using SEM-EDS, FTIR and XRD analysis. A1-4 61% indicator electrode sample coated PVA-enzyme 1x coated with glutaraldehyde (GA) 2.9% 1x coated PVC-KTpClPB- o-NPOE 1x, with o-NPOE 61%. A3-4 61% indicator electrode sample coated PVA-enzyme 3x coated with glutaraldehyde (GA) 2.9% 1x coated PVC-KTpClPB- o-NPOE 1x, with o-NPOE 61%. Likewise, the reasoning of samples A1-4 66% and A3-4 66%. There are four indicator electrodes made with the notation A1-4 61%, A1-4 66%, A3-4 61% and A3-4 66%. The best results were obtained at the indicator electrode sample A1-4 61%, contributing to the urea sensor of the potentiometer cell

References

Alarfaj, N. A., & El-Tohamy, M. F. (2020). New Functionalized Polymeric Sensor Based NiO/MgO Nanocomposite for Potentiometric Determination of Doxorubicin Hydrochloride in Commercial Injections and Human Plasma. In Polymers 12(12). https://doi.org/10.3390/polym12123066.

Alharthi, S. S., Fallatah, A. M., & Al-Saidi, H. M. (2021). Design and Characterization of Electrochemical Sensor for the Determination of Mercury(II) Ion in Real Samples Based upon a New Schiff Base Derivative as an Ionophore. In Sensors 21(9). https://doi.org/10.3390/s21093020.

Al-Mohaimeed, A. M., Mostafa, G. A. E., & El-Tohamy, M. F. (2021). New Construction of Functionalized CuO/Al2O3 Nanocomposite-Based Polymeric Sensor for Potentiometric Estimation of Naltrexone Hydrochloride in Commercial Formulations. In Polymers 13(24). https://doi.org/10.3390/polym13244459.

Amr, A., Kamel, A. H., Almehizia, A. A., Sayed, A., & Abd-Rabboh, H. (2021). Solid-Contact Potentiometric Sensors Based on Main-Tailored Bio-Mimics for Trace Detection of Harmine Hallucinogen in Urine Specimens. Molecules (Basel, Switzerland), 26(2), 324. https://doi.org/10.3390/molecules26020324.

Badakhshan, S., Ahmadzadeh, S., Mohseni-Bandpei, A., Aghasi, M., & Basiri, A. (2019). Potentiometric sensor for iron (III) quantitative determination: experimental and computational approaches. BMC Chemistry, 13(1), 131. https://doi.org/10.1186/s13065-019-0648-x.

Elbehery, N. H. A., Amr, A. E.-G. E., Kamel, A. H., Elsayed, E. A., & Hassan, S. S. M. (2019). Novel Potentiometric 2,6-Dichlorophenolindo-phenolate (DCPIP) Membrane-Based Sensors: Assessment of Their Input in the Determination of Total Phenolics and Ascorbic Acid in Beverages. In Sensors 19(9). https://doi.org/10.3390/s19092058.

El-Naby, E. H. (2019). Potentiometric Signal Transduction for Selective Determination of 1-(3-Chlorophenyl)piperazine “Legal Ecstasy†Through Biomimetic Interaction Mechanism. In Chemosensors 7(3). https://doi.org/10.3390/chemosensors7030046.

Golcs, Ã., Horváth, V., Huszthy, P., & Tóth, T. (2018). Fast Potentiometric Analysis of Lead in Aqueous Medium under Competitive Conditions Using an Acridono-Crown Ether Neutral Ionophore. In Sensors 18(5). https://doi.org/10.3390/s18051407.

Hakim S, A., Sebayang, K., Situmorang, M., Tarigan, K., Sembiring, K., Mihardi, S., & Waruwu, E. (2021). Characterization of indicator electrodes using the potentiometric biosensor method as urea sensor with XRD, SEM-EDS, UV-Vis and FTIR. Journal of Physics: Conference Series, 1816, 12088. https://doi.org/10.1088/1742-6596/1816/1/012088.

Hakim, S.A., Sembiring, T., Tarigan, K., Sebayang, K., Situmorang, M., & Noer, N.M. (2019). Characterization of Membrane PVA-Enzyme Coated PVC-KTpClPB as Urea Sensor with Potentiometric Method. Rasayan Journal of Chemistry, 12, 780–786. https://doi.org/10.31788/RJC.2019.1225143

Hakim, S.A., Tarigan, K., Situmorang, M., & Sembiring, T. (2018). Synthesis of Urea Sensors using Potentiometric Methods with Modification of Electrode Membranes Indicators of ISE from PVA-Enzymes Coating PVC-KTpClPB. Journal of Physics: Conference Series, 1120, 12024. https://doi.org/10.1088/1742-6596/1120/1/012024.

Hassan, S. S. M., H. Kamel, A., Amr, A. E.-G. E., Abd-Rabboh, H. S. M., Al-Omar, M. A., & Elsayed, E. A. (2020). A New Validated Potentiometric Method for Sulfite Assay in Beverages Using Cobalt(II) Phthalocyanine as a Sensory Recognition Element. In Molecules 25(13). https://doi.org/10.3390/molecules25133076.

Hassan, S., Abdelbasir, S. M., Fathy, M. A., Amr, A., Al-Omar, M. A., & Kamel, A. H. (2019). Gold Plate Electrodes Functionalized by Multiwall Carbon Nanotube Film for Potentiometric Thallium(I) Detection. Nanomaterials (Basel, Switzerland), 9(8), 1160. https://doi.org/10.3390/nano9081160.

Hassan, S., H Kamel, A., Amr, A., Hashem, H. M., & Bary, E. (2020). Imprinted Polymeric Beads-Based Screen-Printed Potentiometric Platforms Modified with Multi-Walled Carbon Nanotubes (MWCNTs) for Selective Recognition of Fluoxetine. Nanomaterials (Basel, Switzerland), 10(3), 572. https://doi.org/10.3390/nano10030572.

Huang, S., Luo, F., & Lai, X. (2014), Novel Potentiometric Sensors of Ion Imprinted Polymers for Specific Binding of Yttrium (III), Asian Journal of Chemistry; 26(20). 6787-6790. https://doi.org/10.14233/ajchem.2014.16795

Kamel, A. H., Amr, A. E.-G. E., Ashmawy, N. H., Galal, H. R., Almehizia, A. A., Youssef, T. A., Al-Omar, M. A., & Sayed, A. Y. A. (2020). Validation of a Novel Potentiometric Method Based on a Polymeric PVC Membrane Sensor Integrated with Tailored Receptors for the Antileukemia Drug Cytarabine. In Polymers 12(6). https://doi.org/10.3390/polym12061343.

Kaur, H., Chhibber, M., & Mittal, S. K. (2017). Acyclic Arylamine-Based Ionophores as Potentiometric Sensors for Zn2+ and Ni2+ Ions. In C. 3(4). https://doi.org/10.3390/c3040034.

Mir, M., Lugo, R., Tahirbegi, I. B., & Samitier, J. (2014). Miniaturizable Ion-Selective Arrays Based on Highly Stable Polymer Membranes for Biomedical Applications. In Sensors 14(7). https://doi.org/10.3390/s140711844.

Pomećko, R., Luboch, E., & Jeszke, M. (2021). Dipodal Tetraamide Derivatives of 1,10-Diaza-18-Crown-6 and Alkylmalonic Acids-Synthesis and Use as Ionophores in Ion Selective Membrane Electrodes. Sensors (Basel, Switzerland), 21(15), 4984. https://doi.org/10.3390/s21154984.

Rahman, M. A., Kumar, P., Park, D.-S., & Shim, Y.-B. (2008). Electrochemical Sensors Based on Organic Conjugated Polymers. Sensors, 8(1), 118–141. https://doi.org/10.3390/s8010118.

Rizk, N. M., Abbas, S. S., Hamza, S. M., & Abd El-Karem, Y. M. (2009). Thiopental and Phenytoin as Novel Ionophores for Potentiometric Determination of Lead (II) Ions. Sensors (Basel, Switzerland), 9(3), 1860–1875. https://doi.org/10.3390/s90301860.

Shawky, A. M., & El-Tohamy, M. F. (2021). Highly Functionalized Modified Metal Oxides Polymeric Sensors for Potentiometric Determination of Letrozole in Commercial Oral Tablets and Biosamples. Polymers, 13(9), 1384. https://doi.org/10.3390/polym13091384.

Ulianas, A., Heng, L. Y., & Ahmad, M. (2011). A biosensor for urea from succinimide-modified acrylic microspheres based on reflectance transduction. Sensors (Basel, Switzerland), 11(9), 8323–8338. https://doi.org/10.3390/s110908323

Author Biography

Abd Hakim S, Universitas Negeri Medan

License

Copyright (c) 2022 Abd Hakim S

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

Authors who publish with Jurnal Penelitian Pendidikan IPA, agree to the following terms:

  1. Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution 4.0 International License (CC-BY License). This license allows authors to use all articles, data sets, graphics, and appendices in data mining applications, search engines, web sites, blogs, and other platforms by providing an appropriate reference. The journal allows the author(s) to hold the copyright without restrictions and will retain publishing rights without restrictions.
  2. Authors are able to enter into separate, additional contractual arrangements for the non-exclusive distribution of the journal's published version of the work (e.g., post it to an institutional repository or publish it in a book), with an acknowledgment of its initial publication in Jurnal Penelitian Pendidikan IPA.
  3. Authors are permitted and encouraged to post their work online (e.g., in institutional repositories or on their website) prior to and during the submission process, as it can lead to productive exchanges, as well as earlier and greater citation of published work (See The Effect of Open Access).