Sustainable Green Synthesis Of GO/C-Dots Composites From Tobacco Stem Waste Via Liquid Sonication Exfoliation And Oven Methods
DOI:
10.29303/jppipa.v11i8.11946Published:
2025-08-25Downloads
Abstract
This study investigated the utilization of tobacco stem waste as a green precursor for the synthesis of GO, C-Dots, and GO/C-Dots composites with 1:1 and 1:3 ratios through oven drying methods and liquid sonication exfoliation (LSE). Characterization techniques, including UV-Vis-NIR spectroscopy, XRD, FTIR spectroscopy, SEM, PL, and TRPL, were used to evaluate the synthesized materials. The GO/C-Dots composites exhibited an energy band that classifies them as organic semiconductors. XRD analysis showed a change in crystallinity and indicated an increase in C-Dots content. FTIR analysis showed a shift in functional groups at 1:1 to 1:3 ratios that showed an inverse trend. SEM analysis showed that the addition of C-Dots significantly affected the surface morphology and elemental composition of GO. TRPL test showed consistent results with the trend of PL intensity where C-Dots had the highest value and GO the lowest. This finding highlights the potential of GO/C-Dots composites as sustainable materials, with further exploration needed to assess their applications in various fields such as optoelectronics, catalysis, and environmental science.
Keywords:
Carbon nanodots Graphene oxide Liquid sonication exfoliation Oven heating Waste tobacco sticksReferences
Bragatto, J. N. D. D. B. L. F. (2016). Tobacco stalk as promising feedstock for second generation ethanol production. Bioenergia Em Revista: Diálogos, 6(2). Retrieved from http://fatecpiracicaba.edu.br/revista/index.php/bioenergiaemrevista/article/view/209
Brownson, D. A. C., & Banks, C. E. (2016). Handbook of graphene electrochemistry. Springer. https://doi.org/10.1007/978-1-4471-6428-9
Chai, Y., Feng, Y., Zhang, K., & Li, J. (2022). Preparation of Fluorescent Carbon Dots Composites and Their Potential Applications in Biomedicine and Drug Delivery—A Review. Pharmaceutics, 14(11). https://doi.org/10.3390/pharmaceutics14112482
Dager, A., Baliyan, A., Kurosu, S., Maekawa, T., & Tachibana, M. (2020). Ultrafast synthesis of carbon quantum dots from fenugreek seeds using microwave plasma enhanced decomposition: application of C-QDs to grow fluorescent protein crystals. Scientific Reports, 10(1), 1–15. https://doi.org/10.1038/s41598-020-69264-9
Data Pertanian Provinsi Jawa Tengah. (2019). Data Pusat Statistik Jawa Tengah. Retrieved from https://shorturl.asia/hxSqT
Ding, H., Yu, S. B., Wei, J. S., & Xiong, H. M. (2016). Full-color light-emitting carbon dots with a surface-state-controlled luminescence mechanism. ACS Nano, 10(1), 484–491. https://doi.org/10.1021/acsnano.5b05406
Ditjenbun. (2016). Statistik Perkebunan Indonesia. Ministry of Agriculture, December 2016, 1–79. Retrieved from http://ditjenbun.pertanian.go.id/tinymcpuk/gambar/file/statistik/2016/SAWIT 2014-2016.pdf
Dong, Y., Wang, R., Li, H., Shao, J., Chi, Y., Lin, X., & Chen, G. (2012). Polyamine-functionalized carbon quantum dots for chemical sensing. Carbon, 50(8), 2810–2815. https://doi.org/10.1016/j.carbon.2012.02.046
El-Nahas, S., El-sadek, M. S. A., Salman, H. M., & Elkady, M. M. (2021). Controlled Morphological and Physical Properties of ZnO Nanostructures Synthesized by Domestic Microwave Route. Materials Chemistry and Physics, 258, 123885. https://doi.org/10.1016/j.matchemphys.2020.123885
Georgiopoulou, Z., Verykios, A., Ladomenou, K., Maskanaki, K., Chatzigiannakis, G., Armadorou, K., Palilis, L. C., Chroneos, A., Evangelou, E. K., Gardelis, S., Rashid, A., Coutsolelos, A. G., Aidinis, K., Vasilopoulou, M., & Soultati, A. (2023). Carbon Nanodots as Electron Transport Materials in Organic Light Emitting Diodes and Solar Cells. https://doi.org/10.3390/nano13010169
Giwa, A. S., Chang, F., Xu, H., Zhang, X., Huang, B., Li, Y., Wu, J., Wang, B., Vakili, M., & Wang, K. (2019). Pyrolysis of difficult biodegradable fractions and the real syngas bio-methanation performance. Journal of Cleaner Production, 233, 711–719. https://doi.org/10.1016/j.jclepro.2019.06.145
Handayani, S. S., & Amrullah, A. (2018). Ekstraksi Selulosa Batang Tembakau Sebagai Persiapan Produksi Bioetanol. Jurnal Penelitian Pendidikan IPA, 4(2). https://doi.org/10.29303/jppipa.v4i2.130
Liu, Y., Dong, J., Liu, G., Yang, H., Liu, W., Wang, L., Kong, C., Zheng, D., Yang, J., Deng, L., & Wang, S. (2015). Co-digestion of tobacco waste with different agricultural biomass feedstocks and the inhibition of tobacco viruses by anaerobic digestion. Bioresource Technology, 189, 210–216. https://doi.org/10.1016/j.biortech.2015.04.003
Mu’tamar, M. F. F., Cahyani, I. G., & Fakhry, M. (2018). Application of Liquid Smoke from Tobacco Stem (Nicotiana Tabacum L.) for Shelf Life Extension of Fresh Gourami Fillet. Industria: Jurnal Teknologi Dan Manajemen Agroindustri, 7(3), 181–188. https://doi.org/10.21776/ub.industria.2018.007.03.6
Nugraha, S. P., & Agustiningsih, R. W. (2015). Pelatihan Pemanfaatan Limbah Tembakau Sebagai Bahan Pembuatan Biopestisida Nabati. Inovasi Dan Kewirausahaan, 4(1), 63–67. Retrieved from https://journal.uii.ac.id/ajie/article/view/7897
Sartini. (2019). Sintesis Graphene Oxide Dan Carbon Nanodots Berbahan Dasar Limbah Daun Pisang Kering Dengan Metode Liquid Sonication Exfoliation Dan Pemanasan Oven. [Skripsi. Universitas Negeri Yogyakarta]. Retrieved from https://eprints.uny.ac.id/63781/1/Full%20Skripsi%20Sartini.pdf
Sun, W., Shahrajabian, M. H., & Cheng, Q. (2021). Organic waste utilization and urban food waste composting strategies in china-a review. Notulae Scientia Biologicae, 13(2), 1–16. https://doi.org/10.15835/nsb13210881
Tian, Y., Yu, Z., Cao, L., Zhang, X. L., Sun, C., & Wang, D. W. (2021). Graphene oxide: An emerging electromaterial for energy storage and conversion. Journal of Energy Chemistry, 55, 323–344. https://doi.org/10.1016/j.jechem.2020.07.006
Wang, Y., & Hu, A. (2014). Carbon quantum dots: Synthesis, properties and applications. Journal of Materials Chemistry C, 2(34), 6921–6939. https://doi.org/10.1039/c4tc00988f
License
Copyright (c) 2025 Sabrina Tsaqilatussyifa, Rizka Ekawati, Ahmad Muntako, Firdaus, Deni Aryati, Asmida Herawati

This work is licensed under a Creative Commons Attribution 4.0 International License.
Authors who publish with Jurnal Penelitian Pendidikan IPA, agree to the following terms:
- Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution 4.0 International License (CC-BY License). This license allows authors to use all articles, data sets, graphics, and appendices in data mining applications, search engines, web sites, blogs, and other platforms by providing an appropriate reference. The journal allows the author(s) to hold the copyright without restrictions and will retain publishing rights without restrictions.
- Authors are able to enter into separate, additional contractual arrangements for the non-exclusive distribution of the journal's published version of the work (e.g., post it to an institutional repository or publish it in a book), with an acknowledgment of its initial publication in Jurnal Penelitian Pendidikan IPA.
- Authors are permitted and encouraged to post their work online (e.g., in institutional repositories or on their website) prior to and during the submission process, as it can lead to productive exchanges, as well as earlier and greater citation of published work (See The Effect of Open Access).






