Processing and Characterization of Acrylonitrile Butadiene Styrene (ABS)-Based Biocomposite Filaments Reinforced with Oil Palm Empty Fruit Bunch
DOI:
10.29303/jppipa.v12i3.14177Published:
2026-03-25Downloads
Abstract
The growing demand for sustainable materials in additive manufacturing has driven interest in biocomposite filaments reinforced with natural fillers. In this study, ABS-based biocomposite filaments reinforced with oil palm empty fruit bunch (OPEFB) microfibrillated cellulose were successfully fabricated using a single-screw extrusion process. The OPEFB cellulose content was varied from 0 to 30 wt.% to evaluate its effect on filament dimensional stability, morphology, and chemical structure. Filament extrusion was performed at a processing temperature of 220 °C and an extrusion speed of 850 to ensure stable melt flow and minimize thermal degradation. The results show that the filament diameter remained relatively stable within the range of 2.50-2.80 mm across all compositions, indicating good dimensional control during extrusion. This study highlights the novelty of successfully fabricating ABS-based biocomposite filaments reinforced with OPEFB microfibrillated cellulose using a simple process. SEM analysis revealed that low OPEFB content (2 wt.%) resulted in uniform filler dispersion and good interfacial bonding, while higher filler loadings led to increased porosity, agglomeration, and surface roughness, which may adversely affect filament quality and printability. The current findings demonstrate that OPEFB can enhance filament characteristics even at low composition scales. The presented results are comprehensive enough for initial filament characterization, including dimensional stability, morphology, and chemical structure, which adds to the interest of this study and has not been previously presented. FTIR analysis confirmed that no chemical modification occurred between the ABS matrix and OPEFB cellulose, with interactions dominated by physical bonding. Overall, the findings demonstrate that ABS-OPEFB biocomposite filaments with low to moderate cellulose content can be effectively produced and show potential for fused deposition modeling applications, offering a sustainable alternative to conventional ABS filaments.
Keywords:
Acrylonitrile Butadiene Styrene (ABS) Oil Palm Empty Fruit Bunch (OPEFB) Biocomposite Filament Microfibrillated CelluloseReferences
Abdel Kader, A. H., Fahmy, T. Y., & Kamel, S. (2025). Lignocellulosic reinforced composites: a snapshot of progress. Journal of Wood Chemistry and Technology, 45(4), 167-195. https://doi.org/10.1080/02773813.2025.2538620 DOI: https://doi.org/10.1080/02773813.2025.2538620
Ahmad, I., Baharum, A., & Abdullah, I. (2006). Effect of extrusion rate and fiber loading on mechanical properties of Twaron fiber-thermoplastic natural rubber (TPNR) composites. Journal of reinforced plastics and composites, 25(9), 957-965. https://doi.org/10.1177/0731684406065082 DOI: https://doi.org/10.1177/0731684406065082
Angelopoulos, P. M., Samouhos, M., & Taxiarchou, M. (2021). Functional fillers in composite filaments for fused filament fabrication; a review. Materials Today: Proceedings, 37, 4031-4043. https://doi.org/10.1016/j.matpr.2020.07.069 DOI: https://doi.org/10.1016/j.matpr.2020.07.069
Ariel Leong, J. J., Koay, S. C., Chan, M. Y., Choo, H. L., Tshai, K. Y., & Ong, T. K. (2022). Composite filament made from post-used styrofoam and corn husk fiber for fuse deposition modeling. Journal of Natural Fibers, 19(13), 7033-7048. https://doi.org/10.1080/15440478.2021.1941488 DOI: https://doi.org/10.1080/15440478.2021.1941488
Ariffin H, Norrrahim, M.N.F, Yasim-Anuar, T.A.T, Nishida, H., Hassan, M.A., Ibrahim, N.A. (2017). eOil palm biomass cellulose- fabricated polylactic acid composites for packaging applications. Bionanocomposites Packag Appl. 2017. 5e105. https://doi.org/10.1007/978-3-319-67319-6_5 DOI: https://doi.org/10.1007/978-3-319-67319-6_5
Asyraf, M. R. M., Ishak, M. R., Syamsir, A., Nurazzi, N. M., Sabaruddin, F. A., Shazleen, S. S., ... & Razman, M. R. (2022). Mechanical properties of oil palm fibre-reinforced polymer composites: A review. Journal of Materials Research and Technology, 17, 33-65. https://doi.org/10.1016/j.jmrt.2021.12.122 DOI: https://doi.org/10.1016/j.jmrt.2021.12.122
Banerjee, R., & Ray, S. S. (2023). Role of rheology in morphology development and advanced processing of thermoplastic polymer materials: a review. ACS omega, 8(31), 27969-28001. https://doi.org/10.1021/acsomega.3c03310 DOI: https://doi.org/10.1021/acsomega.3c03310
Berthomieu, C., & Hienerwadel, R. (2009). Fourier transform infrared (FTIR) spectroscopy. Photosynthesis research, 101(2), 157-170. https://doi.org/10.1007/s11120-009-9439-x DOI: https://doi.org/10.1007/s11120-009-9439-x
Cardona, C., Curdes, A. H., & Isaacs, A. J. (2016). Effects of filament diameter tolerances in fused filament fabrication. IU Journal of Undergraduate Research, 2(1), 44-47. https://doi.org/10.14434/iujur.v2i1.20917 DOI: https://doi.org/10.14434/iujur.v2i1.20917
Chan, Y. L., Widodo, R. T., Ming, L. C., Khan, A., Abbas, S. A., Ping, N. Y., ... & Kanakal, M. M. (2025). Review on 3D printing filaments used in fused deposition modeling method for dermatological preparations. Molecules, 30(11), 2411. https://doi.org/10.3390/molecules30112411 DOI: https://doi.org/10.3390/molecules30112411
Costa, I. L., Pereira, P. H., Claro, A. M., Amaral, N. C. D., Barud, H. D. S., Ribeiro, R. B., & Mulinari, D. R. (2023). 3D-printing pen from valorization of pine cone residues as reinforcement in acrylonitrile butadiene styrene (ABS): Microstructure and thermal properties. Journal of Thermoplastic Composite Materials, 36(2), 535-554. https://doi.org/10.1177/08927057211012735 DOI: https://doi.org/10.1177/08927057211012735
Dananjaya, V., Yang, M., Zheng, Y., & Abeykoon, C. (2025). Effect of filler characteristics and processing route on bamboo powder-reinforced PLA composites. Journal of Cleaner Production, 537, 147193. https://doi.org/10.1016/j.jclepro.2025.147193 DOI: https://doi.org/10.1016/j.jclepro.2025.147193
Essabir, H., & Bouhfid, R. (2019). Fracture surface morphologies in understanding of composite structural behavior. In Structural health monitoring of biocomposites, fibre-reinforced composites and hybrid composites (pp. 277-293). Woodhead Publishing. DOI: https://doi.org/10.1016/B978-0-08-102291-7.00014-9
Faruk, O., Bledzki, A. K., Fink, H. P., & Sain, M. (2012). Biocomposites reinforced with natural fibers: 2000–2010. Progress in polymer science, 37(11), 1552-1596. https://doi.org/10.1016/j.progpolymsci.2012.04.003 DOI: https://doi.org/10.1016/j.progpolymsci.2012.04.003
Gupta, V., Bankapalli, N. K., Saxena, P., Bajpai, A., & Ruan, D. (2025). Additive Manufacturing of Fiber‐Reinforced Polymer Matrix Composites through Material Extrusion: A Comprehensive Review on Filament Fabrication, Printing, Testing Methods, Applications, and Challenges. Advanced Engineering Materials, 2500676. https://doi.org/10.1002/adem.202500676 DOI: https://doi.org/10.1002/adem.202500676
Hao, J., Yi, X., Zong, G., Song, Y., Wang, W., Cheng, H., & Wang, G. (2021). Fabrication of long bamboo fiber-reinforced thermoplastic composite by extrusion and improvement of its properties. Industrial Crops and Products, 173, 114120. https://doi.org/10.1016/j.indcrop.2021.114120 DOI: https://doi.org/10.1016/j.indcrop.2021.114120
Ilyas RA, Azmi A, Nurazzi NM, Atiqah A, Atikah MSN, Ibrahim R, et al. Oxygen permeability properties of nanocellulose reinforced biopolymer nanocomposites. Mater Today Proc 2021. https://doi.org/10.1016/j.matpr.2021.10.420 DOI: https://doi.org/10.1016/j.matpr.2021.10.420
Ilyas RA, Sapuan SM, Norrrahim MNF, Yasim-Anuar TAT, Kadier A, Kalil MS, et al. Nanocellulose/starch biopolymer nanocomposites: processing, manufacturing, and applications. In: Al-Oqla FM, Sapuan SM, editors. Adv. Process. Prop. Appl. Starch other bio-based polym. 1st ed. Amsterdam, Netherland: Elsevier; 2020. p. 65e88. https://doi.org/10.1016/B978-0-12-189661-8.00006-8 DOI: https://doi.org/10.1016/B978-0-12-819661-8.00006-8
lyas RA, Sapuan MS, Norizan MN, Norrrahim MNF, Ibrahim R, Atikah MSN, et al. Macro to nanoscale natural fiber composites for automotive components: research, development, and application. In: Sapuan MS, Ily as RA, editors. Biocomposite synth. Compos. Automot. Appl. Amsterdam, Netherland: Woodhead Publishing Series; 2020. DOI: https://doi.org/10.1016/B978-0-12-820559-4.00003-1
Ilyas, R. A., Zuhri, M. Y. M., Aisyah, H. A., Asyraf, M. R. M., Hassan, S. A., Zainudin, E. S., ... & Sari, N. H. (2022). Natural fiber-reinforced polylactic acid, polylactic acid blends and their composites for advanced applications. Polymers, 14(1), 202. https://doi.org/10.3390/polym14010202 DOI: https://doi.org/10.3390/polym14010202
Jalani, N. F., & Zainal, N. H. (2024). Sustainable Biorefinery Concept with Valorization and Utilization of Oil Palm Biomass for Value-Added Products. In Palm Oil Industry: Plantation and Process Towards Circular Economy (pp. 59-77). Singapore: Springer Nature Singapore. https://doi.org/10.1007/978-981-97-7586-6_38 DOI: https://doi.org/10.1007/978-981-97-8277-2_5
Junior, S. A. R., Scherrer, S. S., Ferracane, J. L., & Della Bona, A. (2008). Microstructural characterization and fracture behavior of a microhybrid and a nanofill composite. Dental materials, 24(9), 1281-1288. https://doi.org/10.1016/j.dental.2008.02.006 DOI: https://doi.org/10.1016/j.dental.2008.02.006
Kacem, M. A., Bibb, R., Scarpa, F., & Bodaghi, M. (2025). Sustainable PLA-and bio-epoxy-based bio-composites reinforced with sea urchin residues: from waste to worth. Results in Engineering, 108137. https://doi.org/10.1016/j.rineng.2025.108137 DOI: https://doi.org/10.1016/j.rineng.2025.108137
Khilji, I. A., Chilakamarry, C. R., Surendran, A. N., Kate, K., & Satyavolu, J. (2023). Natural fiber composite filaments for additive manufacturing: a comprehensive review. Sustainability, 15(23), 16171. https://doi.org/10.3390/su152316171 DOI: https://doi.org/10.3390/su152316171
Lamm, M. E., Wang, L., Kishore, V., Tekinalp, H., Kunc, V., Wang, J., ... & Ozcan, S. (2020). Material extrusion additive manufacturing of wood and lignocellulosic filled composites. Polymers, 12(9), 2115. https://doi.org/10.3390/polym12092115 DOI: https://doi.org/10.3390/polym12092115
Lawal AA, Hassan MA, Zakaria MR, Yusoff MZM, Norrrahim MNF, Mokhtar MN, et al. Effect of oil palm biomass cellulosic content on nanopore structure and adsorption capacity of biochar. Bioresour Technol 2021;332:125070. https://doi.org/10.1016/j.biortech.2021.125070 DOI: https://doi.org/10.1016/j.biortech.2021.125070
Mahardika, M., Zakiyah, A., Ulfa, S. M., Ilyas, R. A., Hassan, M. Z., Amelia, D., ... & Norrrahim, M. N. F. (2024). Recent developments in oil palm empty fruit bunch (OPEFB) fiber composite. Journal of Natural Fibers, 21(1), 2309915. https://doi.org/10.1080/15440478.2024.2309915 DOI: https://doi.org/10.1080/15440478.2024.2309915
Mian, S. H., bin Jumah, A., Saleh, M., & Mohammed, J. A. (2025). Fabrication of PLA–Date Fiber Biocomposite via Extrusion Filament Maker for 3D Printing and Its Characterization for Eco-Friendly and Sustainable Applications. Polymers, 17(19), 2707. https://doi.org/10.3390/polym17192707 DOI: https://doi.org/10.3390/polym17192707
Mohan, D., Bakir, A. N., Sajab, M. S., Bakarudin, S. B., Mansor, N. N., Roslan, R., & Kaco, H. (2021). Homogeneous distribution of lignin/graphene fillers with enhanced interlayer adhesion for 3D printing filament. Polymer Composites, 42(5), 2408-2421. DOI: https://doi.org/10.1002/pc.25987
Ng, K. Y., Muhammad, N., Mohd Noor, S. N. F., Rahim, S. Z. A., Saleh, M. S., Muhammad, N. A., ... & Muduli, K. (2025). Effects of fused deposition modeling (FDM) printing parameters on quality aspects of polycaprolactone (PCL) for coronary stent applications: A review. Journal of Biomaterials Applications, 40(3), 327-344. https://doi.org/10.1177/08853282251334880 DOI: https://doi.org/10.1177/08853282251334880
Norrrahim, M.N.F., Kasim, N.A.M., Knight, V.F, Misenan, M.S.M, Janudin N, Shah NAA, (2021). Nanocellulose: a bioadsorbent for chemical contaminant remediation. RSC Adv 2021; 11:7347-68. https://doi.org/10.1039/D0RA08005E DOI: https://doi.org/10.1039/D0RA08005E
Norrrahim MNF, Huzaifah MRM, Farid MAA, Shazleen SS, Misenan MSM, Yasim-Anuar TAT, et al. Greener pretreatment approaches for the valorisation of natural fibre biomass into bioproducts. Polymers 2021;13. DOI: https://doi.org/10.3390/polym13172971
Norrrahim MNF, Yasim-Anuar TAT, Jenol MA, Mohd Nurazzi N, Ilyas RA, Sapuan S. (2020). Performance evaluation of cellulose nanofiber reinforced polypropylene biocomposites for automotive applications. Biocomposite synth. Compos. Automot. Appl. Amsterdam, Netherland: Woodhead Publishing Series; 2020. p. 119-215. DOI: https://doi.org/10.1016/B978-0-12-820559-4.00007-9
Rajendran, N. R., Leong, J. S., Chan, W. N., Tan, J. R., & Shamsuddin, Z. S. B. (2021). Current state and challenges of natural fibre-reinforced polymer composites as feeder in fdm-based 3d printing. Polymers, 13(14), 2289. DOI: https://doi.org/10.3390/polym13142289
Sharip NS, Yasim-Anuar TAT, Norrrahim MNF, Shazleen SS, Nurazzi NM, Sapuan SM, (2020). A review on nanocellulose composites in biomedical application. Compos. Biomed. Appl.. CRC Press; 2020. p. 161e90. DOI: https://doi.org/10.1201/9780429327766-8
Singh, P., Katiyar, P., & Singh, H. (2023). Impact of compatibilization on polypropylene (PP) and acrylonitrile butadiene styrene (ABS) blend: A review. Materials Today: Proceedings, 78, 189-197. DOI: https://doi.org/10.1016/j.matpr.2023.01.350
Tekinalp, H. L., et al. (2014). Highly oriented carbon fiber-polymer composites via additive manufacturing. Composites Science and Technology, 105, 144–150 DOI: https://doi.org/10.1016/j.compscitech.2014.10.009
Thomason, J. L., & Rudeiros-Fernández, J. L. (2018). A review of the impact performance of natural fiber thermoplastic composites. Frontiers in Materials, 5, 60. DOI: https://doi.org/10.3389/fmats.2018.00060
Torrado, A. R., Shemelya, C. M., English, J. D., Lin, Y., Wicker, R. B., & Roberson, D. A. (2015). Characterizing the effect of additives to ABS on the mechanical property anisotropy of specimens fabricated by material extrusion 3D printing. Additive Manufacturing, 6, 16-29. DOI: https://doi.org/10.1016/j.addma.2015.02.001
Yap, L. K., Chun, K. S., Yeng, C. M., Kiat, O. T., Huey, H. S., Hunt, T. C., & Meng, P. M. (2024). Effects of corn husk fiber as filler in recycled single‐use polypropylene for fused filament fabrication. Journal of Vinyl and Additive Technology, 30(2), 620-634. https://doi.org/10.1002/vnl.22074 DOI: https://doi.org/10.1002/vnl.22074
Zakaria Mohd Rafein, Norrrahim MNF, Hirata S, Hassan MA. (2015). Hydrothermal and wet disk milling pretreatment for high conversion of biosugars from oil palm mesocarp fiber. Bioresour Technol 2015; 181: 263e9. https://doi.org/10.1016/j.biortech.2015.01.072 DOI: https://doi.org/10.1016/j.biortech.2015.01.072
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