Manufacture and Characterization of PVA-Enzyme/GA/PANI-HCl or PANI-p-toluentsulfonate/PVC-KTpClPB-o-NPOE Indicator Electrode Membranes, Analysis, XRD, SEM-EDX and FTIR
DOI:
10.29303/jppipa.v9i11.5638Published:
2023-11-25Downloads
Abstract
This research aims at the synthesis and characterization of indicator electrode membranes consisting of PVA-Enzyme/GA/PANI/PVC-KTpClPB-o-NPOE, urea analyte. PANI-HCl and PANI-p-toluensulfonate conducting polymers, 61% and 66% o-NPOE plasticizer variations in PVC-KTpClPB, as well as urease enzyme activity in one or three drops of 0.5 mL PVA (50% water: 50% ethanol). The biosensor potentiometric method was used with the technique of immobilizing the urea enzyme which is the urea analyte. The multi-membrane indicator electrode is PVA-Enzyme/GA/PANI/PVC-KTpClPB-o-NPOE, PANI dissolved in HCl and p-toluensulfonic acid respectively at a concentration of 6 M and 2 M. Each membrane on the indicator electrode is coated with one time. Results of XRD analysis of the spectrum pattern of the PANI-HCl indicator electrode with intensities of 4400 a.u, 1386 a.u, 1724 a.u with a 2theta angle of 28.6 degrees, PANI-p-toluensulfonate with intensities of 10940 a.u, 9194 a.u, 5312 a.u with a 2theta angle of 18.2 degrees. SEM-EDX analysis showed differences in the morphology of the o-NPOE plasticizer of 61% and 66% as well as an increase in cps/eV from the number of drops of the urease enzyme, one drop was lower than three drops. FTIR analysis shows an increase in transmittance by PANI towards PPy. Analysis of the properties of a multi-membrane indicator electrode with one layer of the best sample is PANI-p-toluensulfonate
Keywords:
Elektroda indicator HCl Multi membrane PVA-Enzim/GA/PANI/PVC-KTpClPB-o-NPOE p-toluensulfonatReferences
Aizamddin, M. F., Mahat, M. M., Zainal Ariffin, Z., Nawawi, M. A., Jani, N. A., Nor Amdan, N. A., & Sadasivuni, K. K. (2022). Antibacterial Performance of Protonated Polyaniline-Integrated Polyester Fabrics. Polymers, 14(13), 2617. https://doi.org/10.3390/polym14132617
Alipour, A., Mansour Lakouraj, M., & Tashakkorian, H. (2021). Study of the effect of band gap and photoluminescence on biological properties of polyaniline/CdS QD nanocomposites based on natural polymer. Scientific Reports, 11(1), 1913. https://doi.org/10.1038/s41598-020-80038-1
Beygisangchin, M., Abdul Rashid, S., Shafie, S., & Sadrolhosseini, A. R. (2021). Polyaniline Synthesized by Different Dopants for Fluorene Detection via Photoluminescence Spectroscopy. Materials, 14(23), 7382. https://doi.org/10.3390/ma14237382
Bohari, N. A., Siddiquee, S., Saallah, S., Misson, M., & Arshad, S. E. (2020). Optimization and Analytical Behavior of Electrochemical Sensors Based on the Modification of Indium Tin Oxide (ITO) Using PANI/MWCNTs/AuNPs for Mercury Detection. Sensors, 20(22), 6502. https://doi.org/10.3390/s20226502
Dulgerbaki, C. (2023). Development of Poly(2-Methyl Thioaniline)/Vanadium Pentoxide Hybrid Electrode Material for High Performance Supercapacitor Applications. Journal of Macromolecular Science, Part B, 62(9), 504–513. https://doi.org/10.1080/00222348.2023.2232250
Elbehery, N. H. A., Amr, A. E.-G. E., Kamel, A. H., Elsayed, E. A., & Hassan, S. S. M. (2019). Novel Potentiometric 2,6-Dichlorophenolindo-phenolate (DCPIP) Membrane-Based Sensors: Assessment of Their Input in the Determination of Total Phenolics and Ascorbic Acid in Beverages. Sensors, 19(9), 2058. https://doi.org/10.3390/s19092058
Gamal, A., Shaban, M., BinSabt, M., Moussa, M., Ahmed, A. M., Rabia, M., & Hamdy, H. (2022). Facile Fabrication of Polyaniline/Pbs Nanocomposite for High-Performance Supercapacitor Application. Nanomaterials, 12(5), 817. https://doi.org/10.3390/nano12050817
Gao, H., Cai, M., & Liao, Y. (2019). Enhance photocatalytic properties of TiO 2 using π-π* conjugate system. Journal of Dispersion Science and Technology, 40(10), 1469–1478. https://doi.org/10.1080/01932691.2018.1518143
Guerrero, J., Carrillo, A., Mota, M., Ambrosio, R., & Aguirre, F. (2018). Purification and Glutaraldehyde Activation Study on HCl-Doped PVA–PANI Copolymers with Different Aniline Concentrations. Molecules, 24(1), 63. https://doi.org/10.3390/molecules24010063
Hakim S, A. (2022). Characterization of PVA-Enzyme Coated Indicator Electrodes GA coated again with PVC-KTpClPB-o-NPOE SEM-EDS, FTIR and XRD analysis. Jurnal Penelitian Pendidikan IPA, 8(1), 103–108. https://doi.org/10.29303/jppipa.v8i1.1265
Hakim S, A. (2023). Synthesis and Characterization of PVA-Enzyme/GA/PPy/ PVC-KTpClPB-o-NPOE Indicator Electrodes, XRD Analysis, FTIR and Variable Signal Analysis. Jurnal Penelitian Pendidikan IPA, 9(3), 1149–1154. https://doi.org/10.29303/jppipa.v9i3.2389
Hsu, P.-Y., Hu, T.-Y., Kumar, S., Wu, K., & Lue, S. (2022). Swelling-Resistant, Crosslinked Polyvinyl Alcohol Membranes with High ZIF-8 Nanofiller Loadings as Effective Solid Electrolytes for Alkaline Fuel Cells. Nanomaterials, 12(5), 865. https://doi.org/10.3390/nano12050865
Katowah, D. F., Saleh, S. M., Alqarni, S. A., Ali, R., Mohammed, G. I., & Hussein, M. A. (2021). Network structure-based decorated CPA@CuO hybrid nanocomposite for methyl orange environmental remediation. Scientific Reports, 11(1), 5056. https://doi.org/10.1038/s41598-021-84540-y
Kaur, H., Chhibber, M., & Mittal, S. (2017). Acyclic Arylamine-Based Ionophores as Potentiometric Sensors for Zn2+ and Ni2+ Ions. C, 3(4), 34. https://doi.org/10.3390/c3040034
Li, C. (2017). Advanced Nanomaterials for Renewable Energy and Sustainability, The Dissertation of Changling Li is approved. University of California Riverside.
Munaji, Zainuri, M., & Triwikantoro. (2023). Structures and electric properties of PANI/polymorphic-ZrO 2 composites. RSC Advances, 13(15), 10414–10423. https://doi.org/10.1039/D3RA01088K
Nawaz, S., Siddiq, M., Kausar, A., Hussain, S. T., & Abbas, F. (2014). Facile Synthesis and Properties of Multilayered Polyaniline/Polypyrrole/Epoxy/Polystyrene/Functionalized Carbon Nanotube Composites. Polymer-Plastics Technology and Engineering, 53(7), 661–670. https://doi.org/10.1080/03602559.2013.874032
Pan, Y., Hu, S., Zheng, X., Hu, N., Qiu, F., Dai, M., Guo, Q., Yu, X., Hao, Y., Lv, M., & Huang, J. (2023). Efficient electromagnetic interference shielding of three-dimensional hydrophobic Cu/wood/Cu porous composites. Journal of Wood Chemistry and Technology, 43(4), 206–220. https://doi.org/10.1080/02773813.2023.2213691
Pani, A., Lee, J. H., & Yun, S. I. (2016). Autoclave mediated one-pot-one-minute synthesis of AgNPs and Au-Ag nanocomposite from Melia azedarach bark extract with antimicrobial activity against food pathogens. Chemistry Central Journal, 10(1). https://doi.org/10.1186/s13065-016-0157-0
Qiu, B., Wang, J., Li, Z., Wang, X., & Li, X. (2020). Influence of Acidity and Oxidant Concentration on the Nanostructures and Electrochemical Performance of Polyaniline during Fast Microwave-Assisted Chemical Polymerization. Polymers, 12(2), 310. https://doi.org/10.3390/polym12020310
Terán-Alcocer, Ã., Bravo-Plascencia, F., Cevallos-Morillo, C., & Palma-Cando, A. (2021). Electrochemical Sensors Based on Conducting Polymers for the Aqueous Detection of Biologically Relevant Molecules. Nanomaterials, 11(1), 252. https://doi.org/10.3390/nano11010252
Tudose, I. V., Mouratis, K., Ionescu, O. N., Romanitan, C., Pachiu, C., Popescu, M., Khomenko, V., Butenko, O., Chernysh, O., Kenanakis, G., Barsukov, V. Z., Suchea, M. P., & Koudoumas, E. (2022). Novel Water-Based Paints for Composite Materials Used in Electromagnetic Shielding Applications. Nanomaterials, 12(3), 487. https://doi.org/10.3390/nano12030487
Usman, F., Dennis, J. O., Meriaudeau, F., Ahmed, A. Y., Seong, K. C., Fen, Y. W., Sadrolhosseini, A. R., Abdulkadir, B. A., Ayinla, R. T., Daniyal, W. M. E. M. M., Omar, N. A. S., Tamam, N., & Sulieman, A. (2020). Dependence of the Optical Constant Parameters of p-Toluene Sulfonic Acid-Doped Polyaniline and Its Composites on Dispersion Solvents. Molecules, 25(19), 4414. https://doi.org/10.3390/molecules25194414
Usman, M., Adnan, M., Ahsan, M. T., Javed, S., Butt, M. S., & Akram, M. A. (2021). In Situ Synthesis of a Polyaniline/ Fe-Ni Codoped Co3O4Composite for the Electrode Material of Supercapacitors with Improved Cyclic Stability. ACS Omega, 6(2), 1190–1196. https://doi.org/10.1021/acsomega.0c04306
Vlascici, D., Cosma, E. F., Pica, E. M., Cosma, V., Bizerea, O., Mihailescu, G., & Olenic, L. (2008). Free base porphyrins as ionophores for heavy metal sensors. Sensors, 8(8), 4995–5004. https://doi.org/10.3390/s8084995
Yao, J., Chen, Y., Li, W., Chen, X., & Fan, X. (2019). Fabrication and characterization of electrospun PLLA/PANI/TSA fibers. RSC Advances, 9(10), 5610–5619. https://doi.org/10.1039/C8RA10495F
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