Experimental and Theoretical Studies of Black Cumin Seed (Nigella sativa) Extract as Corrosion Inhibitor for ASTM A36 Steel
DOI:
10.29303/jppipa.v10i12.8565Published:
2024-12-31Downloads
Abstract
Black cumin seed extract (Nigella sativa) is effective to control ASTM A36 steel corrosion in 1 M HCl solution. This study analyzed black cumin seed (BCS) extract as a corrosion inhibitor (0 to 500 ppm) by electrochemical method including Potentiodynamic Polarization (PDP) and Electrochemical Impedance Spectroscopy (EIS). The results revealed that with the PDP method the highest inhibition efficiency (IE) was 84.26% at the concentration of 500 ppm, and with the EIS method the IE value was 77.77% at the same concentration. The components of the extract were analyzed by GCMS and obtained major compounds are linoleic acid (22.12%), methyl linoleate (22.70%), 4-cyclopentene-1,3-dione,4-3-methyl-2-butenyl) (7.64%), methyl palmitate (6.66%), and palmitic acid (5.14%). A theoretical approach with computation was also carried out to investigate the performance and interaction of the major compounds in the BCS extract that a significant role as inhibitor. This was using Density Functional Theory (DFT) method and Monte Carlo simulation. The results showed that methyl linoleate compound as the most significant role.
Keywords:
Black Cumin Seed (Nigella sativa), Corrosion Inhibitor, EIS, DFT, Monte Carlo, PDPReferences
Alrashidi, M., Derawi, D., Salimon, J., & Yusoff, F.(2020). An Investigation of Physicochemical Preperties of Nigella sativa L. Seed Oil from Al-Qassim by Different Extraction Methods. Journal of King Saud University-Science. https://doi.org/10.1016/j.jksus.2020.09.019
Chellouli, M., Chebabe, D., Dermaj, A., Erramli, H., Bettach, N., Hajjaji, N., Casaletto, M. P., Cirrincione, C., Privitera, A., & Srhiri, A. (2016). Corrosion Inhibition of Iron in Acidic Solution by a Green Formulation Derived from Nigella sativa L, Electrochimica Acta, 204, 50–59. https://doi.org/10.1016/j.electacta.2016.04.015
Döner, A., Solmaz, R., Özcan, M., & Kardaş, G. (2011). Experimental and Theoretical Studies of Thiazoles as Corrosion Inhibitors for Mild Steel in Sulphuric Acid Solution, Corrosion Science, 53(9), 2902–2913. https://doi.org/10.1016/j.corsci.2011.05.02
El Hajjaji, F., Greche, H., Taleb, M., Chetouani, A., Aouniti, A., & Hammouti, B. (2016) Application of Essential Oil of Thyme vulgaris as Green Corrosion Inhibitor for Mild Steel in 1 MHCl, Journal of Materials and Environmental Science, 7(2), 567–578.
Gapsari, F., Setyarini, P. H., Kurniawan, F., Ahnaf, A., Anwar, M. S., & Zuryati, U. S. (2022). Corrosion Inhibition of Weldment by Nephelium lappaceum Peel Extract in 3.5% NaCl Solution. South African Journal of Chemical Engineering, 41, 223-232. https://doi.org/10.1006/j.sajce.2022.06.006.
Gapsari, F., Styarini, P. H., Utariningrum, F., Sulaiman, A M., Haidar, M. F., & Julian, T. S. (2024). Melaleuca Leaves Extract as Eco-Friendly Inhibitor for Low carbon Steel in Sulfuric Acid. Case Studies in Chemical and Environment Engineering, 9, 100657. https://doi.org/10/1016/j.cscee.2024.100657.
H., K., L., A., & M., M. (2018). Comparative Assessment of Extraction Methods and Quantitative Estimation of Thymoquinone in The Seeds of Nigella sativa L By HPLC, International Journal of Pharmacognosy and Phytochemical Research, 9(12), 1425–1428. https://doi.org/10.25258/phyto.v9i12.11186
Hadisaputra, S., Hamdiani, S., Kurniawan, M. A., & Nuryono, N. (2017). Influence of Macrocyclic Ring Size on The Corrosion Inhibition Efficiency of Dibenzo Crown Ether: A Density Functional Study, Indonesian Journal of Chemistry, 17(3), 431–438. https://doi.org/10.22146/ijc.26667
Hadisaputra, S., Purwoko, A. A., & Hamdiani, S. (2022). Copper Corrosion Protection by 4-Hydrocoumarin Derivatives: Insight from Density Functional Theory, Ab Initio, and Monte Carlo Simulation Studies, Indonesian Journal of Chemistry, 22(2), 413–428. https://doi.org/10.22146/ijc.69530
Hadisaputra, S., Purwoko, A. A., Rahmawati, Asnawati, D., Ilhamsyah, Hamdiani, S., & Nuryono. (2019). Experimental and Theoretical Studies of (2R)-5-hydroxy-7-methoxy-2-phenyl-2,3-dihydrochromen-4-one as Corrosion Inhibitor for Iron in Hydrochloric Acid, International Journal of Electrochemical Science, 14, 11110–11121. https://doi.org/10.20964/2019.12.77
Hadisaputra, S., Purwoko, A. A., Savalas, L. R. T., Prasetyo, N., Yuanita, E., dan Hamdiani, S. (2020). Quantum Chemical and Monte Carlo Simulation Studies on Inhibition Performance of Caffeine and Its Derivatives Against Corrosion of Copper, Coatings, 10(11), 1–17. https://doi.org/10.3390/coatings10111086
Hassan, H., Ismail, A., Ahmad., S., & Soon, C. F. (2017). Super-Hydrophobic Corrosion Inhibitor on Carbon Steel, Materials Science and Enginering, 215, 1-5.
Hidayatullah, S., Gapsari, F., & Setyarini, P. H. (2019). ASTM A36 Iron Corrosion Behavior in Hydrochloric Acid (HCl) with Fish Scale Chitosan Inhibitor. National Seminar on Innovation and Application of Technology in Industry
Hsissou, R., Abbout, S., Seghiri, R., Rehioui, M., Berisha, A., Erramli, H., Assouag, M., & Elharfi, A. (2020). Evaluation of Corrosion Inhibition Performance of Phosphorus Polymer for Carbon Steel in [1 M] HCl: Computational Studies (DFT, MC and MD simulations), Journal of Materials Research and Technology, 9(3), 2691–2703. https://doi.org/10.1016/j.jmrt.2020.01.002
Jiang, L., Qiang, Y., Lei, Z., Wang, J., Qin, Z., & Xiang, B. (2018). Excellent Corrosion Inhibition Performance of Novel Quinoline Derivatives on Mild Steel in HCl Media: Experimental and Computational Investigations, Journal of Molecular Liquids, 255(2017), 53–63. https://doi.org/10.1016/j.molliq.2018.01.133
Kabir, Y., Akasaka-Hashimoto, Y., Kubota, K., & Komai, M. (2020). Volatile Compounds of Black Cumin (Nigella sativa L.) Seeds Cultivated in Bangladesh and India, Heliyon, 6(10), e05343. https://doi.org/10.1016/j.heliyon.2020.e05343
Kardas, G., & Yazıcı, B. (2014). Electrochemical and Quantum Chemical Studies of 2-amino-4-methyl-thiazole as Corrosion Inhibitor for Mild Steel in HCl Solution. https://doi.org/10.1016/j.corsci.2014.02.029
Lashgari, S. M., Bahlakeh, G., & Ramezanzadeh, B. (2021). Detailed Theoretical DFT Computation/Molecular Simulation and Electrochemical Extrapolations of Thymus vulgaris Leave Extract for Effective Mild-Steel Corrosion Retardation in HCl Solution. Journal of Molecular Liquids, 335, 115897. https://doi.org/10.1016/j.molliq.2021.115897
Lgaz, H., Chung, I. M., Albayati, M. R., Chaouiki, A., Salghi, R., & Mohamed, S. K. (2020). Improved Corrosion Resistance of Mild Steel in Acidic Solution by Hydrazone Derivatives: An Experimental and Computational Study, Arabian Journal of Chemistry, 13(1), 2934–2954. https://doi.org/10.1016/j.arabjc.2018.08.004
Mulyati, B., Si, S., & Si, M. (2019), Tanin dapat Dimanfaatkan sebagai Inhibitor Korosi.
Obot, I. B., Solomon, M. M., Umoren, S. A., Suleiman, R., Elanany, M., Alanazi, N. M., & Sorour, A. A. (2019). Progress in The Development of Sour Corrosion Inhibitors: Past, Present, and Future Perspectives, Journal of Industrial and Engineering Chemistry, 79, 1–18. https://doi.org/10.1016/j.jiec.2019.06.046
Prasad, A. R., Kunyankandy, A., & Joseph, A. (2020). Corrosion Inhibition in Oil and Gas Industry: Economic Considerations, Corrosion Inhibitors in The Oil and Gas Industry, 135–150. https://doi.org/10.1002/9783527822140.ch5
Salarvand, Z., Amirnasr, M., Talebian, M., Raeissi, K., & Meghdadi, S. (2017). Enhanced Corrosion Resistance of Mild Steel in 1 M HCl Solution by Trace amount of 2-phenyl-benzothiazole Derivatives: Experimental, Quantum Chemical Calculations and Molecular Dynamics (MD) Simulation Studies, In Corrosion Science (Vol. 114). Elsevier Ltd. https://doi.org/10.1016/j.corsci.2016.11.002
Saleh, M. M., Mahmoud, M. G., & El-Lateef, H. M. (2019). Comparative Study of Synergistic Inhibition of Mild Steel and Pure Iron by 1-hexadecylpyridium Chloride and Bromide Ions. Corrosion Science, 154, 70-79. https://doi.org/10.1016/j.corsci.2019.03.048
Samal, P. P., Singh, C. P., & Krishnamurty, S. (2023). Expounnding Lemonal Terpenoids as Corrosion Inhibitors for Copper Using DFT Based Calculations, Journal Applied Surface Science, 614, 156066
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