Supercapacitors from Reduced Graphene Oxide Material

Authors

Maryati Doloksaribu , Makmur Sirait , Erniwati Halawa , Mukti Hamjah Harahap

DOI:

10.29303/jppipa.v11i4.11027

Published:

2025-04-25

Issue:

Vol. 11 No. 4 (2025): April

Keywords:

Graphite, Optical Properties, Reduced graphene oxide, Supercapacitor, Synthesis

Research Articles

Downloads

How to Cite

Doloksaribu, M., Sirait, M., Halawa, E., & Harahap, M. H. (2025). Supercapacitors from Reduced Graphene Oxide Material . Jurnal Penelitian Pendidikan IPA, 11(4), 202–208. https://doi.org/10.29303/jppipa.v11i4.11027

Downloads

Download data is not yet available.

Metrics

Metrics Loading ...

Abstract

Reduced graphene oxide (rGO) has been chemically synthesized from graphite powder. Graphite powder is oxidized using a strong oxidizing compound to obtain graphite oxide, this process is called the Hummer Method. Graphite oxide is dispersed using an ultrasonic vibrator to peel off the graphite oxide layer and become graphene oxide. The epoxy group in graphite oxide is reduced using 80 wt% hydrazine compound at temperatures of 70????, 80 and 90????C to obtain reduced graphene oxide. Then rGO is characterized using Uv-Vis spectroscopy, and FTIR. The Uv-Vis spectrum shows that the absorbance of rGO decreases with increasing reduction temperature. Then the absorbance data is calculated for its optical constant using the Kramers-Kronig Method. The refractive index values ​​of the real and imaginary parts of the calculation results show that in the low energy region an increase in the optical constant value is obtained with the addition of rGO. Then rGO was used in supercapacitor fabrication using PVA as a binder, 1 M ????2????????4 electrolyte, and aluminum foil as a collector and the supercapacitor mass was obtained as much as 0.01 grams. From the cyclic voltammetry measurement, the capacitor capacitance value was obtained as much as 24.5 F/gr.

References

Banerjee, K., & Shukla. (2013). Influence of binder solvent on carbon-layer structure in electrical-double-layer capacito. Ournal of Chemical Sciences, 125, 1177–1183. https://doi.org/10.1007/s12039-013-0494-7

Berger, C., Song, Z., & dkk. (2004). Ultrathin Epitaxial Graphite: 2D Electron Gas Properties and a Route toward Graphene-based Nanoelectronics. Journal of Physical Chemistry B, 108, 6106. https://doi.org/10.1021/jp040650f

Chen, Z., & Yu, dan M. A. (2010). High performance supercapacitors based on reduced graphene oxide in aqueous and ionic liquid electrolytes. Carbon, 40, 573–580. https://doi.org/10.1016/j.carbon.2010.09.060

Dreyer, D. R., Park, S., Bielawski, C. W., & Ruoff, R. S. (2010). The chemistry of graphene oxide. Chemical Society Reviews, 39(1), 228–240. https://doi.org/10.1039/B917103G

El-Kady, M. F., Strong, V., Dubin, S., & Kaner, R. B. (2012). Laser scribing of high-performance and flexible graphene-based electrochemical capacitors. Science, 335(6074), 1326–1330. https://doi.org/10.1126/science.1216744

Elias, D. C., Nair, R. R., Mohiuddin, T. M. G., Morozov, S. V, Blake, P., Halsall, M. P., Ferrari, A. C., Boukhvalov, D. W., Katsnelson, M. I., Geim, A. K., & others. (2009). Control of graphene’s properties by reversible hydrogenation: evidence for graphane. Science, 323(5914), 610–613. https://doi.org/10.1126/science.1167130

Fox, M. (2010). Optical Properties of Solids. New York: Oxford University Press.

Geim, A. K., & Novoselov, K. S. (2007). The rise of graphene. Nature Materials, 6(3), 183–191. Retrieved from https://www.nature.com/articles/nmat1849

Huang, L., Chia, Y., & Muhammad. (2011). Simple room-temperature preparation of high-yield large-area graphene oxide. Journal of Nanomedicine, 6, 3443–3448. https://doi.org/10.2147/IJN.S26812

Iqbal, M., Ali, M., & Khan, M. A. (2024). Supercapacitors: An emerging energy storage system. Advanced Energy and Sustainability Research, 5(4), 2400412. https://doi.org/10.1002/aesr.202400412

Khan, M. A., Kumar, A., Zhang, J., & Kumar, M. (2021). Recent advances and prospects in reduced graphene oxide-based photodetectors. Journal of Materials Chemistry C, 9(26), 8129–8157. https://doi.org/10.1039/D1TC01306H

Kumar, A., Singh, R., & Patel, S. (2024). A review of supercapacitors: Materials, technology, challenges, and renewable energy applications. Journal of Energy Storage, 96, 112563. https://doi.org/10.1016/j.est.2024.112563

Nair, R. R., Blake, P., Grigorenko, A. N., Novoselov, K. S., Booth, T. J., Stauber, T., Peres, N. M. R., & Geim, A. K. (2008). Fine structure constant defines visual transparency of graphene. Science, 320(5881), 1308. https://doi.org/10.1126/science.1156965

Nam, P. T., Khanh, N., Thom, N. T., Phuong, N. T., Trang, N., Xuyen, N. T., & Mai Thanh, D. T. (2018). Synthesis of reduced graphene oxide for high-performance supercapacitor. Vietnam Journal of Chemistry, 56(6), 778–785. https://doi.org/10.1002/vjch.201800087

Pei, S., & Cheng, H.-M. (2012). The reduction of graphene oxide. Carbon, 50(9), 3210–3228. https://doi.org/10.1016/j.carbon.2011.11.010

Pham, V. H., & Dickerson, J. H. (2016). Reduced graphene oxide hydrogels deposited in nickel foam for supercapacitor applications: Toward high volumetric capacitance. The Journal of Physical Chemistry C, 120(10), 5353–5360. https://doi.org/10.1021/acs.jpcc.6b00326

Prekodravac, M., Jovanovic, A., & Pavlovic, T. (2016). Raman spectroscopy study of graphene thin film synthesized from solid precursor. Opt Quant Electron, 48(115). https://doi.org/10.1007/s11082-016- 0385-5

Rajagopalan, B., & Chung, J. S. (2014). Reduced chemically modified graphene oxide for supercapacitor electrode. Nanoscale Research Letters, 9(1), 535. https://doi.org/10.1186/1556-276X-9-535

Ramabadran, U., Ryan, G., Zhou, X., Farhat, S., Manciu, F., Tong, Y., Ayler, R., & Garner, G. (2017). Reduced graphene oxide on nickel foam for supercapacitor electrodes. Materials, 10(11), 1295. https://doi.org/10.3390/ma10111295

Rasul, S., Alazmi, A., Jaouen, K., Hedhili, M. N., & Costa, P. M. F. J. (2017). Rational design of reduced graphene oxide for superior performance of supercapacitor electrodes. Carbon, 111, 774–781. https://doi.org/10.1016/j.carbon.2016.10.066

Raza, H. (2012). Graphene Nanoelectronic: Metrology, Synthesis, Properties and Application. New York: Springer.

Ren, Y., & Ji, dan L. (2011). Temperature dependence of graphene oxide reduced by hydrazine hydrate. Nanotech. https://doi.org/10.1088/0957-4484/22/5/055705

Şahin, M. E., Blaabjerg, F., & Sangwongwanich, A. (2022). A comprehensive review on supercapacitor applications and developments. Energies, 15(3), 674. https://doi.org/10.3390/en15030674

Santoso, I., Singh, G., Asmara, W., Chen, W., & Pereira, dan R. (2014). Effect of oxygen plasma on the optical properties of monolayer graphene. Advanced Materials Research, 896, 510–513. https://doi.org/10.4028/www.scientific.net/AMR.896.510

Shulga, B., Volfkovich, S., Parkhomenko, B., Gutsev, R., & Sosenkin, dan K. (2015). Supercapacitors with graphene oxide separators and reduced graphite oxide electrodes. Journal of Power of Source, 279, 722–730. https://doi.org/10.1016/j.jpowsour.2015.01.032

Simon, P., & Gogotsi, Y. (2008). Materials for electrochemical capacitors. Nature Materials, 7(11), 845–854. https://doi.org/10.1038/nmat2297

Sindi, A. M. (2024). Applications of graphene oxide and reduced graphene oxide in advanced dental materials and therapies. Journal of Taibah University Medical Sciences, 19(2), 403–421. https://doi.org/10.1016/j.jtumed.2024.02.002

Smith, A. T., LaChance, A. M., Zeng, S., Liu, B., & Sun, L. (2019). Synthesis, properties, and applications of graphene oxide/reduced graphene oxide and their nanocomposites. Nano Materials Science, 1(1), 31–47. https://doi.org/10.1016/j.nanoms.2019.02.004

Stoller, M. D., Park, S., Zhu, Y., An, J., & Ruoff, R. S. (2008). Graphene-based ultracapacitors. Nano Letters, 8(10), 3498–3502. https://doi.org/10.1021/nl802558y

Stoller, M. D., & Ruoff, R. S. (2010). Best practice methods for determining an electrode material’s performance for ultracapacitors. Energy & Environmental Science, 3(9), 1294–1301. https://doi.org/10.1039/C0EE00074D

Strimaitis, J., Danquah, S. A., Denize, C. F., Pradhan, S. K., & Bahoura, M. (2022). The effects of graphene oxide and reduced graphene oxide conductive additives on activated carbon supercapacitors. Processes, 10(11), 2190. https://doi.org/10.3390/pr10112190

Tarcan, R., Todor-Boer, O., Petrovai, I., Leordean, C., Astilean, S., & Botiz, I. (2020). Reduced graphene oxide today. Journal of Materials Chemistry C, 8(4), 1198–1224. https://doi.org/10.1039/C9TC04916A

Wang, C., Zhang, C., Tian, G., & Xu. (2014). Fabrication of PVA/Graphene oxide/TiO2 composite nanofibers through electrospinning and interface sol-gel reaction: Effect of graphene oxide on PVA nanofibers and growth of TiO2. Journal of Colloid and Surface A, 457, 318–325. https://doi.org/10.1016/j.colsurfa.2014.06.006

Wang, H., Casalongue, H. S., Liang, Y., & Dai, H. (2011). Ni(OH)2 nanoplates grown on graphene as advanced electrochemical pseudocapacitor materials. Journal of the American Chemical Society, 132(21), 7472–7477. https://doi.org/10.1021/ja102267j

Wu, Q., Xu, Y., Yao, Z., Liu, A., & Shi, G. (2010). Supercapacitors Based on Flexible Graphene/Polyaniline Nanofiber Composite Films. ACS Nano, 4. https://doi.org/10.1021/nn1000035

Xiao, J. R., Gillespie, J. W., & Mikhailov, S. (2011). Physics and Applications of Graphene-Theory. InTech Publisher.

Zhang, L. L., & Zhao, X. (2009). Carbon-based materials as supercapacitor electrodes. Chemical Society Reviews, 38(9), 2520–2531. https://doi.org/10.1039/B813846J

Author Biographies

Maryati Doloksaribu, Universitas Negeri Medan

Makmur Sirait, Universitas Negeri Medan

Erniwati Halawa, Universitas Negeri Medan

Mukti Hamjah Harahap, Universitas Negeri Medan

License

Copyright (c) 2025 Maryati Doloksaribu, Makmur Sirait, Erniwati Halawa, Mukti Hamjah Harahap

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

Authors who publish with Jurnal Penelitian Pendidikan IPA, agree to the following terms:

  1. Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution 4.0 International License (CC-BY License). This license allows authors to use all articles, data sets, graphics, and appendices in data mining applications, search engines, web sites, blogs, and other platforms by providing an appropriate reference. The journal allows the author(s) to hold the copyright without restrictions and will retain publishing rights without restrictions.
  2. Authors are able to enter into separate, additional contractual arrangements for the non-exclusive distribution of the journal's published version of the work (e.g., post it to an institutional repository or publish it in a book), with an acknowledgment of its initial publication in Jurnal Penelitian Pendidikan IPA.
  3. Authors are permitted and encouraged to post their work online (e.g., in institutional repositories or on their website) prior to and during the submission process, as it can lead to productive exchanges, as well as earlier and greater citation of published work (See The Effect of Open Access).