Synthesis and Characterization of PVA-Enzyme/GA/PPy/ PVC-KTpClPB-o-NPOE Indicator Electrodes, XRD Analysis, FTIR and Variable Signal Analysis

Authors

Abd Hakim S

DOI:

10.29303/jppipa.v9i3.2389

Published:

2023-03-31

Issue:

Vol. 9 No. 3 (2023): March

Keywords:

Multi-membrane, Enzyme modification, PVA-Enzyme/GA/PPy/PVC- KTpClPB-o-NPOE, H2SO4, Potentiometer cell

Research Articles

Downloads

How to Cite

Hakim S, A. (2023). Synthesis and Characterization of PVA-Enzyme/GA/PPy/ PVC-KTpClPB-o-NPOE Indicator Electrodes, XRD Analysis, FTIR and Variable Signal Analysis. Jurnal Penelitian Pendidikan IPA, 9(3), 1149–1154. https://doi.org/10.29303/jppipa.v9i3.2389
Crossref
Scopus
Google Scholar
Europe PMC

Downloads

Download data is not yet available.

Metrics

Metrics Loading ...

Abstract

This study aims to synthesize and characterize PVA-Enzyme/GA/PPy/PVC-KTpClPB-o-NPOE indicator indicator electrodes, XRD and FTIR analysis and variable signal analysis for urea sensors. The method used is biosensor potentiometry with urease enzyme immobilization technique which analytes urea. Modify 6 mg of enzyme from the amount of 1 drop and 3 drops in 0.5 mL (50% water: 50% ethanol) in PVA solution and o-NPOE plasticizer in PVC-KTpClPB. The indicator electrode is designed in multi-membrane, namely PVA-Enzyme/GA/PPy/PVC-KTpClPB-o-NPOE. PPy was dissolved in H2SO4 at a concentration of 8 M. Modification of PVA-Enzyme/(GA 2.9%)/PVC-KTpClPB-(o-NPOE 61%) was carried out in one layer each. The number of enzyme drops to see the difference in the intensity of the XRD diffraction spectrum and the difference in the transmittance of the FTIR spectrum from the indicator electrode with multi membrane modified PPy with H2SO4 denoted H2SO4-1 and H2SO4-3, respectively. The best results were obtained on the indicator electrode with the notation H2SO4-1

References

Abd-Rabboh, H. S., M. Hashem, H., MS Al Shagri, L., E. Amr, A. E. G., Almehizia, A. A., Naglah, A. M., & H. Kamel, A. (2022). All-Solid-State Potentiometric Platforms Modified with a Multi-Walled Carbon Nanotubes for Fluoxetine Determination. Membranes, 12(5), 446. https://doi.org/10.3390/membranes12050446

Badakhshan, S., Ahmadzadeh, S., Mohseni-Bandpei, A., Aghasi, M., & Basiri, A. (2019). Potentiometric sensor for iron (III) quantitative determination: experimental and computational approaches. BMC chemistry, 13(1), 1-12. https://doi.org/10.1186/s13065-019-0648-x.

Basile, A., Bhatt, A. I., & O’Mullane, A. P. (2016). Stabilizing lithium metal using ionic liquids for long-lived batteries. Nature communications, 7(1), ncomms11794. https://doi.org/10.1038/ncomms11794.

Bié, J., Sepodes, B., Fernandes, P. C., & Ribeiro, M. H. (2022). Enzyme immobilization and co-immobilization: Main framework, advances and some applications. Processes, 10(3), 494. https://doi.org/10.3390/pr10030494.

Dacrory, S., Saeed, A. M., & Abouzeid, R. E. (2022). A novel ammonia sensor based on cellulose/graphene oxide functionalized with ethylenediamine. Express Polymer Letters, 16(8), 786-797. https://doi.org/10.3144/expresspolymlett.2022.58

Elbehery, N. H., Amr, A. E. G. E., Kamel, A. H., Elsayed, E. A., & Hassan, S. S. (2019). Novel potentiometric 2, 6-dichlorophenolindo-phenolate (dcpip) membrane-based sensors: Assessment of their input in the determination of total phenolics and ascorbic acid in beverages. Sensors, 19(9), 2058. https://doi.org/10.3390/s19092058.

Hakim S. A., (2021). Characterization of PVA-Enzyme Coated Indicator Electrodes GA coated again with PVC-KTpClPB-o-NPOE UV-Vis analysis, variable signal analysis, sensor sensitivity and SEM-EDS. JPPIPA, 7(Special Issue), 248. https://doi.org/10.29303/jppipa.v7iSpecialIssue.1248.

Hakim S., A, Mihardi, S., A Rais, A., Willy, & Panjaitan, Y. T. H. (2022). Characterization of manufacturing indicator electrodes coated PVA-enzyme coated 1X GA and 3X GA 2.9 % coated PVC-KTpClPB coated using potentiometry method. Journal of Physics: Conference Series, 2165(1), 012042. https://doi.org/10.1088/1742-6596/2165/1/012042.

Hakim S.A., Situmorang, M., Sebayang, K., Sembiring, T., Tarigan, K., Mihardi, S., Noor, N.M., & Elnovreny, J., (2021). Characterization of Urea Analyte Solution and Electrolyte Solution Using Non-Immobilized Electrode Indicators and PVA-Enzyme Coated PVC-KTpClPB Immobilization. RASAYAN J. Chem, 14(2), 1356-1368. https://doi.org/10.31788/RJC.2021.1426103.

He, T., Li, X., Wang, Q., Zhou, Y., Wang, X., Wang, Z., ... & Cui, Z. (2022). Poly (vinylidene fluoride) (PVDF) membrane fabrication with an ionic liquid via non-solvent thermally induced phase separation (N-TIPs). Applied Water Science, 12(3), 42. https://doi.org/10.1007/s13201-021-01499-x.

Hsu, P. Y., Hu, T. Y., Kumar, S. R., Wu, K. C. W., & Lue, S. J. (2022). Swelling-resistant, crosslinked polyvinyl alcohol membranes with high ZIF-8 nanofiller loadings as effective solid electrolytes for alkaline fuel cells. Nanomaterials, 12(5), 865. https://doi.org/10.3390/nano12050865.

Jaziri, A. A., Shapawi, R., Mokhtar, R. A. M., Noordin, W. N. M., & Huda, N. (2022). Biochemical analysis of collagens from the bone of lizardfish (Saurida tumbil Bloch, 1795) extracted with different acids. PeerJ, 10, e13103. https://doi.org/10.7717/peerj.13103.

Kaur, H., Chhibber, M., & Mittal, S. K. (2017). Acyclic arylamine-based ionophores as potentiometric sensors for Zn2+ and Ni2+ ions. Basel, 3(4), 34. https://doi.org/10.3390/c3040034.

Kim, E., Liu, Z., Liu, Y., Bentley, W. E., & Payne, G. F. (2017). Catechol-based hydrogel for chemical information processing. Biomimetics, 2(3), 11. https://doi.org/10.3390/biomimetics2030011.

Lenar, N., Piech, R., & Paczosa-Bator, B. (2022). Hydrous Cerium Dioxide-Based Materials as Solid-Contact Layers in Potassium-Selective Electrodes. Membranes, 12(4), 349. https://doi.org/10.3390/membranes12040349.

Mohamed, R. R., Fahim, M. E., & Soliman, S. (2022). Development of hydrogel based on Carboxymethyl cellulose/poly (4-vinylpyridine) for controlled releasing of fertilizers. BMC chemistry, 16(1), 1-12. https://doi.org/10.1186/s13065-022-00846-6.

Rahman, M. A., Kumar, P., Park, D. S., & Shim, Y. B. (2008). Electrochemical sensors based on organic conjugated polymers. Sensors, 8(1), 118-141. https://doi.org/10.3390/s8010118.

Saeed, W. S., Alotaibi, D. H., Al-Odayni, A. B., Haidyrah, A. S., Al-Owais, A. A., Khan, R., ... & Aouak, T. (2022). Poly (ethylene-Co-vinyl Alcohol)/Titanium Dioxide Nanocomposite: Preparation and Characterization of Properties for Potential Use in Bone Tissue Engineering. International Journal of Molecular Sciences, 23(7), 3449. https://doi.org/10.3390/ijms23073449.

Vlascici, D., Fagadar Cosma, E., Pica, E. M., Cosma, V., Bizerea, O., Mihailescu, G., & Olenic, L. (2008). Free base porphyrins as ionophores for heavy metal sensors. Sensors, 8(8), 4995-5004. https://doi.org/10.3390/s8084995.

Author Biography

Abd Hakim S, Universitas Negeri Medan

License

Copyright (c) 2023 Abd Hakim S

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

Authors who publish with Jurnal Penelitian Pendidikan IPA, agree to the following terms:

  1. Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution 4.0 International License (CC-BY License). This license allows authors to use all articles, data sets, graphics, and appendices in data mining applications, search engines, web sites, blogs, and other platforms by providing an appropriate reference. The journal allows the author(s) to hold the copyright without restrictions and will retain publishing rights without restrictions.
  2. Authors are able to enter into separate, additional contractual arrangements for the non-exclusive distribution of the journal's published version of the work (e.g., post it to an institutional repository or publish it in a book), with an acknowledgment of its initial publication in Jurnal Penelitian Pendidikan IPA.
  3. Authors are permitted and encouraged to post their work online (e.g., in institutional repositories or on their website) prior to and during the submission process, as it can lead to productive exchanges, as well as earlier and greater citation of published work (See The Effect of Open Access).