Raman Spectroscopy for Non-Destructive Detection of Pesticide on Guava Peel
DOI:
10.29303/jppipa.v9i4.3202Published:
2023-04-30Issue:
Vol. 9 No. 4 (2023): AprilKeywords:
Guava, Laser, Pesticide, Raman, SpectroscopyResearch Articles
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Abstract
Pesticides are one of the substances that are widely used to protect plants from pests and plant diseases, and their use must be controlled for the public health. Currently, the pesticide contamination is determined by chromatographic, but this technique is destructive and not easy to implement. Therefore, this research is proposed to overcome these problems. Raman scattering technique as a non-destructive testing technique and easy to implement is used in this research. This technique utilizes Raman scattering resulting from laser excitation in a sample. Pesticide detection was carried out by observing the difference in Raman shift wavelength between samples containing pesticides and samples that did not contain pesticides. The experiments were done on guava peels with coated pesticide delthametrin 25 g/l. By excitation with laser wavelengths 532 nm and 785 nm, the differences in Raman shifts at wavelengths 1,225 nm and 1,480 for samples coated pesticide, and Raman shifts at wavelengths 1,008 nm and 1,480 nm for samples which is treated are obtained, respectively. From this research, it can be concluded that Raman scattering technique can be used as non-destructive and easy technique for detection pesticide contamination.
References
Badrudin, U., Jazilah, S., & Prakoso, B. (2022). The effect of soil submersion and conditioner materials on residual organophosphate pesticides in soil and shallot bulbs. Agrivita, 44(1), 1. http://doi.org/10.17503/agrivita.v41i0.1291
Buwono, N. R., Gultom, T., Ayuning, S. W., & Supriatna, S. (2019). Bioakumulasi residu pestisida pada komunitas gastropoda di perairan Sungai Kalisat, Kabupaten Malang. Depik, 8(3), 167-175. https://doi.org/10.13170/depik.8.3.14368
Cortese, M., Gigliobianco, M. R., Magnoni, F., Censi, R., & Di Martino, P. (2020). Compensate for or minimize matrix effects? Strategies for overcoming matrix effects in liquid chromatography-mass spectrometry technique: a tutorial review. Molecules, 25(13), 3047. https://doi.org/10.3390/molecules25133047
Dong, T., Lin, L., He, Y., Nie, P., Qu, F. and Xiao, S. (2018). Density Functional Theory Analysis of Deltamethrin and Its Application in Strawberry by Surface-Enhanced Raman Spectroscopy. Molecules, (23), 1458. https://doi.org/10.3390/molecules23061458
Duniaji, A., & Suter, I. (2021). Pengujian Kandungan Residu Pestisida Pada Tanaman Sayuran Di Kabupaten Badung Dengan Kartu Pendeteksi Pestisida (Pesticide Detection Cards) Dan Gas Chromatography Mass Spectrophotometry. Jurnal Ilmu Dan Teknologi Pangan (ITEPA), 10(4), 746-752. https://doi.org/10.24843/itepa.2021.v10.i04.p19
Hassan, M. M., Li, H., Ahmad, W., Zareef, M., Wang, J., Xie, S., ... & Chen, Q. (2019). Au@ Ag nanostructure based SERS substrate for simultaneous determination of pesticides residue in tea via solid phase extraction coupled multivariate calibration. Lwt, 105, 290-297. https://doi.org/10.1016/j.lwt.2019.02.016
Hendriadi, A., Sulistiyorini, & Devilana, M. R. (2021). Pesticides residues in fresh food of plant origin:Study case in Indonesia. AGRIVITA Journal of Agricultural Science, 43(2), 285–299. https://doi.org/10.17503/agrivita.v43i2.2570
Hidayah, A. N., Herbani, Y., Triyono, D., & Saleh, R. (2022). Effect of Yield Silver Nanoparticles in Enhancing Raman Signal of SERS Substrate Fabricated on Whatman Filter Paper. Journal of Physics and Its Applications, 4(2), 47-50. https://doi.org/10.14710/jpa.v4i2.13226
Kurnia, A. (2018). Analisis Residu Klorpirifos pada Tanah dan Validasinya. Agrikultura, 29(2), 61-65. https://doi.org/10.24198/agrikultura.v29i2.19247
Kurnia, N., Kholik, K., & Khaeruman, K. (2023). Mapping Chemical Hazards in Animal Food Origin Product for Food Safety Teaching Materials. Jurnal Penelitian Pendidikan IPA, 9(1), 455-461.. https:// doi.org/10.29303/jppipa.v9i1.2534
Malan, D., Van Der Walt, S. J., & Rohwer, E. R. (2020). A high-repetition-rate, fast temperature-programmed gas chromatograph and its online coupling to a supercritical fluid chromatograph (SFC× GC). Review of Scientific Instruments, 91(3), 034101. https://doi.org/10.1063/1.5125060
Nurhalisa, N., Arfiati, D., Andayani, S., Osa, A., & Nadiro, V. N. (2023). Insecticide with the active ingredient methomyl interferes with the growth and survival of the jatiumbulan tilapia strain (Oreochromis niloticus). Jurnal Penelitian Pendidikan IPA, 9(2), 485-490. https:// doi.org/ 10.29303/jppipa.v9i2.2928
Osaili, T. M., Al Sallagi, M. S., Dhanasekaran, D. K., Odeh, W. A. B., Al Ali, H. J., Al Ali, A. A., ... & Obaid, R. S. (2022). Pesticide residues in fresh fruits imported into the United Arab Emirates. Heliyon, 8(12), e11946. https://doi.org/10.1016/j.heliyon.2022.e11946
Septaningsih, D. A., Darusman, L. K., Afendi, F. M., & Heryanto, R. (2018). Liquid chromatography mass spectrometry (LC-MS) fingerprint combined with chemometrics for identification of metabolites content and biological activities of curcuma aeruginosa. Indonesian Journal of Chemistry, 18(1), 43-52. https://doi.org/10.22146/ijc.25456
Tankiewicz, M., & Berg, A. (2022). Improvement of the QuEChERS method coupled with GC–MS/MS for the determination of pesticide residues in fresh fruit and vegetables. Microchemical Journal, 181, 107794. https://doi.org/10.1016/j.microc.2022.107794
Tegegne, W. A., Su, W. N., Tsai, M. C., Beyene, A. B., & Hwang, B. J. (2020). Ag nanocubes decorated 1T-MoS2 nanosheets SERS substrate for reliable and ultrasensitive detection of pesticides. Applied Materials Today, 21, 100871. https://doi.org/10.1016/j.apmt.2020.100871
Umayah, A., & Wagiyanti, W. (2021). Cara Penggunaan Pestisida dan Analisis Residu pada Cabai Merah (Capsicum annuum L.)(Studi Kasus: Desa Saleh Mukti, Kecamatan Air Salek, Kabupaten Banyuasin). Agrikultura, 32(1), 57-62. https://doi.org/10.24198/agrikultura.v32i1.32566
Versari, A., Sukendra, D. M., & Wulandhari, S. A. (2021). Overview of Domestic and Agricultural Pesticides Use Contributing to Aedes aegypti Resistence in Ambarawa Subdistrict, Indonesia. Unnes Journal of Public Health, 10(1), 100-109. https://doi.org/10.15294/ujph.v10i1.39923
Vutrianingsih, N. E., Zulfa, I., & Mukono, J. (2020). Risk Factors Related To Carbamate And Organophosphate Pesticide Poisoning In Rice Farmers In Masangan Kulon Village, Sidoarjo District. The Indonesian Journal of Public Health, 191-200, http://dx.doi.org/10.20473/ijph.v15i2.2020.190-200
Yulianto, E., Chatterjee, S., & Mizeikis, V. (2019). Characterization of Latent 3D Laser Photoexposure Patterns in Photoresist Created by Direct Laser Writing. Materials Today: Proceedings, 13, 149-153. https://doi.org/10.1016/j.matpr.2019.03.205
Yulianto, E., Chatterjee, S., Purlys, V., & Mizeikis, V. (2019). Imaging of latent three-dimensional exposure patterns created by direct laser writing in photoresists. Applied Surface Science, 479, 822-827. https://doi.org/10.1016/j.apsusc.2019.02.033
Zhang, A. A., Sutar, P. P., Bian, Q., Fang, X. M., Ni, J. B., & Xiao, H. W. (2022). Pesticide residue elimination for fruits and vegetables: the mechanisms, applications, and future trends of thermal and non-thermal technologies. Journal of Future Foods, 2(3), 223-240. https://doi.org/10.1016/j.jfutfo.2022.06.004
Author Biographies
Edy Yulianto, Politeknik Teknologi Nuklir Indonesia
Marsetiayu Ningsih, 2National Research and Innovation Agency (BRIN)
Wahyu Bahari, National Research and Innovation Agency (BRIN)
Ahmad Musthofa, National Research and Innovation Agency (BRIN)
Galuh Prihantoro, National Research and Innovation Agency (BRIN)
Fifit Astuti, Pamulang University
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Copyright (c) 2023 Edy Yulianto, Marsetiayu Ningsih, Wahyu Bahari, Ahmad Musthofa, Galuh Prihantoro, Fifit Astuti
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