Raman Spectroscopy for Non-Destructive Detection of Pesticide on Guava Peel

Authors

Edy Yulianto , Marsetiayu Ningsih , Wahyu Bahari , Ahmad Musthofa , Galuh Prihantoro , Fifit Astuti

DOI:

10.29303/jppipa.v9i4.3202

Published:

2023-04-30

Issue:

Vol. 9 No. 4 (2023): April

Keywords:

Guava, Laser, Pesticide, Raman, Spectroscopy

Research Articles

Downloads

How to Cite

Yulianto, E., Ningsih, M. ., Bahari, W. ., Musthofa, A. ., Prihantoro, G. ., & Astuti, F. . (2023). Raman Spectroscopy for Non-Destructive Detection of Pesticide on Guava Peel. Jurnal Penelitian Pendidikan IPA, 9(4), 2025–2029. https://doi.org/10.29303/jppipa.v9i4.3202

Downloads

Download data is not yet available.

Metrics

Metrics Loading ...

Abstract

Pesticides are one of the substances that are widely used to protect plants from pests and plant diseases, and their use must be controlled for the public health. Currently, the pesticide contamination is determined by chromatographic, but this technique is destructive and not easy to implement. Therefore, this research is proposed to overcome these problems. Raman scattering technique as a non-destructive testing technique and easy to implement is used in this research. This technique utilizes Raman scattering resulting from laser excitation in a sample. Pesticide detection was carried out by observing the difference in Raman shift wavelength between samples containing pesticides and samples that did not contain pesticides. The experiments were done on guava peels with coated pesticide delthametrin 25 g/l. By excitation with laser wavelengths 532 nm and 785 nm, the differences in Raman shifts at wavelengths 1,225 nm and 1,480 for samples coated pesticide, and Raman shifts at wavelengths 1,008 nm and 1,480 nm for samples which is treated are obtained, respectively. From this research, it can be concluded that Raman scattering technique can be used as non-destructive and easy technique for detection pesticide contamination.

References

Badrudin, U., Jazilah, S., & Prakoso, B. (2022). The effect of soil submersion and conditioner materials on residual organophosphate pesticides in soil and shallot bulbs. Agrivita, 44(1), 1. http://doi.org/10.17503/agrivita.v41i0.1291

Buwono, N. R., Gultom, T., Ayuning, S. W., & Supriatna, S. (2019). Bioakumulasi residu pestisida pada komunitas gastropoda di perairan Sungai Kalisat, Kabupaten Malang. Depik, 8(3), 167-175. https://doi.org/10.13170/depik.8.3.14368

Cortese, M., Gigliobianco, M. R., Magnoni, F., Censi, R., & Di Martino, P. (2020). Compensate for or minimize matrix effects? Strategies for overcoming matrix effects in liquid chromatography-mass spectrometry technique: a tutorial review. Molecules, 25(13), 3047. https://doi.org/10.3390/molecules25133047

Dong, T., Lin, L., He, Y., Nie, P., Qu, F. and Xiao, S. (2018). Density Functional Theory Analysis of Deltamethrin and Its Application in Strawberry by Surface-Enhanced Raman Spectroscopy. Molecules, (23), 1458. https://doi.org/10.3390/molecules23061458

Duniaji, A., & Suter, I. (2021). Pengujian Kandungan Residu Pestisida Pada Tanaman Sayuran Di Kabupaten Badung Dengan Kartu Pendeteksi Pestisida (Pesticide Detection Cards) Dan Gas Chromatography Mass Spectrophotometry. Jurnal Ilmu Dan Teknologi Pangan (ITEPA), 10(4), 746-752. https://doi.org/10.24843/itepa.2021.v10.i04.p19

Hassan, M. M., Li, H., Ahmad, W., Zareef, M., Wang, J., Xie, S., ... & Chen, Q. (2019). Au@ Ag nanostructure based SERS substrate for simultaneous determination of pesticides residue in tea via solid phase extraction coupled multivariate calibration. Lwt, 105, 290-297. https://doi.org/10.1016/j.lwt.2019.02.016

Hendriadi, A., Sulistiyorini, & Devilana, M. R. (2021). Pesticides residues in fresh food of plant origin:Study case in Indonesia. AGRIVITA Journal of Agricultural Science, 43(2), 285–299. https://doi.org/10.17503/agrivita.v43i2.2570

Hidayah, A. N., Herbani, Y., Triyono, D., & Saleh, R. (2022). Effect of Yield Silver Nanoparticles in Enhancing Raman Signal of SERS Substrate Fabricated on Whatman Filter Paper. Journal of Physics and Its Applications, 4(2), 47-50. https://doi.org/10.14710/jpa.v4i2.13226

Kurnia, A. (2018). Analisis Residu Klorpirifos pada Tanah dan Validasinya. Agrikultura, 29(2), 61-65. https://doi.org/10.24198/agrikultura.v29i2.19247

Kurnia, N., Kholik, K., & Khaeruman, K. (2023). Mapping Chemical Hazards in Animal Food Origin Product for Food Safety Teaching Materials. Jurnal Penelitian Pendidikan IPA, 9(1), 455-461.. https:// doi.org/10.29303/jppipa.v9i1.2534

Malan, D., Van Der Walt, S. J., & Rohwer, E. R. (2020). A high-repetition-rate, fast temperature-programmed gas chromatograph and its online coupling to a supercritical fluid chromatograph (SFC× GC). Review of Scientific Instruments, 91(3), 034101. https://doi.org/10.1063/1.5125060

Nurhalisa, N., Arfiati, D., Andayani, S., Osa, A., & Nadiro, V. N. (2023). Insecticide with the active ingredient methomyl interferes with the growth and survival of the jatiumbulan tilapia strain (Oreochromis niloticus). Jurnal Penelitian Pendidikan IPA, 9(2), 485-490. https:// doi.org/ 10.29303/jppipa.v9i2.2928

Osaili, T. M., Al Sallagi, M. S., Dhanasekaran, D. K., Odeh, W. A. B., Al Ali, H. J., Al Ali, A. A., ... & Obaid, R. S. (2022). Pesticide residues in fresh fruits imported into the United Arab Emirates. Heliyon, 8(12), e11946. https://doi.org/10.1016/j.heliyon.2022.e11946

Septaningsih, D. A., Darusman, L. K., Afendi, F. M., & Heryanto, R. (2018). Liquid chromatography mass spectrometry (LC-MS) fingerprint combined with chemometrics for identification of metabolites content and biological activities of curcuma aeruginosa. Indonesian Journal of Chemistry, 18(1), 43-52. https://doi.org/10.22146/ijc.25456

Tankiewicz, M., & Berg, A. (2022). Improvement of the QuEChERS method coupled with GC–MS/MS for the determination of pesticide residues in fresh fruit and vegetables. Microchemical Journal, 181, 107794. https://doi.org/10.1016/j.microc.2022.107794

Tegegne, W. A., Su, W. N., Tsai, M. C., Beyene, A. B., & Hwang, B. J. (2020). Ag nanocubes decorated 1T-MoS2 nanosheets SERS substrate for reliable and ultrasensitive detection of pesticides. Applied Materials Today, 21, 100871. https://doi.org/10.1016/j.apmt.2020.100871

Umayah, A., & Wagiyanti, W. (2021). Cara Penggunaan Pestisida dan Analisis Residu pada Cabai Merah (Capsicum annuum L.)(Studi Kasus: Desa Saleh Mukti, Kecamatan Air Salek, Kabupaten Banyuasin). Agrikultura, 32(1), 57-62. https://doi.org/10.24198/agrikultura.v32i1.32566

Versari, A., Sukendra, D. M., & Wulandhari, S. A. (2021). Overview of Domestic and Agricultural Pesticides Use Contributing to Aedes aegypti Resistence in Ambarawa Subdistrict, Indonesia. Unnes Journal of Public Health, 10(1), 100-109. https://doi.org/10.15294/ujph.v10i1.39923

Vutrianingsih, N. E., Zulfa, I., & Mukono, J. (2020). Risk Factors Related To Carbamate And Organophosphate Pesticide Poisoning In Rice Farmers In Masangan Kulon Village, Sidoarjo District. The Indonesian Journal of Public Health, 191-200, http://dx.doi.org/10.20473/ijph.v15i2.2020.190-200

Yulianto, E., Chatterjee, S., & Mizeikis, V. (2019). Characterization of Latent 3D Laser Photoexposure Patterns in Photoresist Created by Direct Laser Writing. Materials Today: Proceedings, 13, 149-153. https://doi.org/10.1016/j.matpr.2019.03.205

Yulianto, E., Chatterjee, S., Purlys, V., & Mizeikis, V. (2019). Imaging of latent three-dimensional exposure patterns created by direct laser writing in photoresists. Applied Surface Science, 479, 822-827. https://doi.org/10.1016/j.apsusc.2019.02.033

Zhang, A. A., Sutar, P. P., Bian, Q., Fang, X. M., Ni, J. B., & Xiao, H. W. (2022). Pesticide residue elimination for fruits and vegetables: the mechanisms, applications, and future trends of thermal and non-thermal technologies. Journal of Future Foods, 2(3), 223-240. https://doi.org/10.1016/j.jfutfo.2022.06.004

Author Biographies

Edy Yulianto, Politeknik Teknologi Nuklir Indonesia

Marsetiayu Ningsih, 2National Research and Innovation Agency (BRIN)

Wahyu Bahari, National Research and Innovation Agency (BRIN)

Ahmad Musthofa, National Research and Innovation Agency (BRIN)

Galuh Prihantoro, National Research and Innovation Agency (BRIN)

Fifit Astuti, Pamulang University

License

Copyright (c) 2023 Edy Yulianto, Marsetiayu Ningsih, Wahyu Bahari, Ahmad Musthofa, Galuh Prihantoro, Fifit Astuti

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

Authors who publish with Jurnal Penelitian Pendidikan IPA, agree to the following terms:

  1. Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution 4.0 International License (CC-BY License). This license allows authors to use all articles, data sets, graphics, and appendices in data mining applications, search engines, web sites, blogs, and other platforms by providing an appropriate reference. The journal allows the author(s) to hold the copyright without restrictions and will retain publishing rights without restrictions.
  2. Authors are able to enter into separate, additional contractual arrangements for the non-exclusive distribution of the journal's published version of the work (e.g., post it to an institutional repository or publish it in a book), with an acknowledgment of its initial publication in Jurnal Penelitian Pendidikan IPA.
  3. Authors are permitted and encouraged to post their work online (e.g., in institutional repositories or on their website) prior to and during the submission process, as it can lead to productive exchanges, as well as earlier and greater citation of published work (See The Effect of Open Access).